How Sunlight Shortens Product Lifespan

Science predicts durability timelines for materials exposed to solar radiation

Explore the Science

Sunlight is not only a source of life and warmth but also a powerful factor in material degradation. Under its influence, automotive polymer parts lose strength, paint coatings fade, and even cut flowers wilt quickly. Predicting product durability under solar radiation is a complex scientific task combining materials science, climatology, and mathematical modeling.

Why Sunlight Degrades Materials: Physics and Chemistry of the Process

Solar radiation, especially its ultraviolet component (UV radiation), initiates complex physical-chemical processes on the surface and within materials.

Degradation Mechanisms

  • Photolytic reactions - direct destruction of molecules under UV radiation
  • Photo-oxidation - material oxidation with participation of sunlight and atmospheric oxygen
  • Thermo-oxidative degradation - accelerated oxidation due to material heating by solar rays
  • Changes in polymer crystallinity - reorganization of supramolecular structure leading to brittleness

Thermal State Role

The thermal state of a product, formed under solar radiation and heat exchange with the environment, is crucial. Mathematical modeling of non-stationary thermal state allows predicting the equivalent operating temperature—the constant temperature that would cause the same level of material degradation as real changing conditions 1 .

Gelendzhik Experiment: Testing Material Resistance

One of the most authoritative centers for studying climate impact on materials is the Gelendzhik Center for Climate Testing named after G.V. Akimov (GCKI VIAM).

Gelendzhik Testing Conditions

4956 MJ/m²

Annual solar radiation dose

72%

Average air humidity

C3 (Medium)

Corrosion category for steel

Experimental Methodology

Sample Preparation

Steel plates undergo abrasive blasting (Sa 2.5 according to ISO 8501-1) to ensure adhesion. A coating system is applied: zinc-rich primer, intermediate, and finish enamel layers with total thickness of 150-200 μm 7 .

Exposure

Samples are placed on atmospheric stands at a 45° angle to the horizon, 20 meters from the water's edge, ensuring exposure to both solar radiation and sea salts 7 .

Monitoring

Using a meteorological complex (16 atmospheric parameter sensors) and hydrological complex (15 water parameters), continuous measurements are taken of solar radiation intensity, air temperature and humidity, wind speed and direction, sample surface temperature, and chloride concentration in the air 4 .

Degradation Assessment

At specific intervals, samples undergo visual inspection and instrumental measurements: color change (CIELAB system), chalking appearance (ISO 4628-6), rust appearance (ISO 4628-3), blistering (ISO 4628-2), and adhesion loss (ISO 4624) 7 .

Results and Analysis

Comparative Atmospheric Corrosivity Data 4
Location Climate Zone Radiation Dose (MJ/m²) Corrosion Category
Gelendzhik Center Moderately Warm 4956 C3 (Medium)
Tropical Station Tropical ~5500 C5 (Very High)
Temperate Station Temperate ~3500 C2 (Low)
Polyurethane Coating Results After 24 Months 7
Atmosphere Type Color Change, ΔE Chalking Rust Adhesion, MPa
Marine (Gelendzhik) 3.2 1 0 4.5
Industrial 5.8 2 1 3.8
Rural (Clean) 2.1 0 0 4.9
Predicted Service Life of Polyurethane Coating Systems 7

Scientific Toolkit: Research Methods and Tools

A combination of methods—from field testing to accelerated laboratory tests and mathematical modeling—is used to predict durability timelines.

Finite Element Method for Thermal Modeling

Perm Polytechnic University developed the TeSunRad algorithm and program for calculating non-stationary thermal state of complex-shaped products considering solar radiation. The method is based on the variational formulation of the heat conduction problem and its implementation through the finite element method (FEM) 1 .

Accelerated Climate Testing

To reduce research time, artificial climate chambers are widely used, reproducing the effects of solar radiation, temperature, and humidity in an accelerated mode.

Research Method Reproduced Factors Advantages Disadvantages
Field Testing Full range of natural factors Maximum reliability Long duration (years)
Cyclic Testing Temperature, humidity, UV, SO₂, salt fog Factor combination Weak correlation for some materials
UV Chamber Testing UV radiation, temperature, humidity Speed, controlled conditions Simplified simulation

Key Research Equipment and Materials

Pyranometers

Sensors for measuring solar radiation intensity 5

UV Lamps

UV radiation sources in aging chambers 6

Thermocouples

Temperature and humidity control sensors

Chemical Reagents

For creating specific environments (salt solutions, SO₂ gas mixtures)

Practical Applications: From Aviation to Floristry

Durability prediction finds applications across diverse industries, enabling better product design and maintenance strategies.

Aviation & Engineering

Calculation of equivalent operating temperatures helps predict the service life of polymer materials in machines and structures operating in natural conditions 1 . This is critical for ensuring safety and reliability.

Construction

Evaluation of coating weather resistance helps select optimal protection for structures in various climates—from seacoasts to industrial areas 7 .

Agriculture & Floristry

Sunlight accelerates wilting of cut flowers. Integrating weather data into accounting systems allows predicting shelf life of different flower varieties, optimizing purchases and logistics, and reducing spoilage losses 3 .

Future of Durability Prediction

Predicting product durability under solar radiation has transformed from art to science. Modern mathematical modeling methods combined with field and accelerated testing allow highly accurate predictions of material behavior in real operating conditions.

New Models

Accounting for factor synergy

Climate Stations

Expanded testing network

Better Equipment

Improved testing chambers

System Integration

Business process optimization

References